You can factor the left hand side to get 14m+21n = 100 7*(2m+3n) = 100 7*x = 100 where x = 2m+3n is an integer
There are no solutions to 7x = 100 since 7 is not a factor of 100 (ie 7|100 is false). So that means there are no solutions to the original diophantine equation.